Cannot Change Appearance in Control Center, and Caja will not Launch

Do I get it right your problem manifested itself and by itself since you upgraded from UM 22.04 to UM 24.04? If yes, then it casts some doubt whether Mate DE reinstallation may help. Well, if live CD session works as intended, some hope remains still.

Side note: I had an unpleasant experience of crippling my desktop completely. In the end of the day I had to backup my files from home directory and installed the whole OS from scratch.

IMHO, to completely remove Mate DE you need to

apt-get purge --autoremove mate-desktop

As to installation, the following links may be of interest

https://linuxconfig.org/how-to-install-mate-desktop-on-ubuntu-20-04-focal-fossa-linux

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