I have installed Compton and enabled it through Mate Tweak. I expected since there is integration that it would now just work at startup, though that isn't the case. I also tried adding Compton to Startup Applications, though that has still had no effect. Running Compton from the terminal after a reboot returns the following:
vsync_opengl_swc_init(): I'm afraid glXSwapIntervalSGI wouldn't help if you are not using GLX backend. You could try, nonetheless. Another composite manager is already running
I realise its no longer officially supported, but I would appreciate any input anyway.
Thanks folks.