I'm an aussie, and until this month (Oct 2022) I've always had bandwidth quota restrictions on my home internet. My ISP also provides an official mirror of the Ubuntu repositories and they allowed that to be used quota-free, and until about a year ago official Ubuntu ISOs (but not flavors) could be downloaded quota-free. As a result; for as long as I've been using Ubuntu (since 10.10) my install was always with Ubuntu ISOs (ie. Ubuntu Desktop, Ubuntu Server), then I'd adjust to use the ISPs mirror so as to be quota-free, then add the desktop(s) I really wanted to use. This bandwidth quota issue at home introduced me to having multiple desktops, and I decided I loved it 
(for awhile I used to remove the default Ubuntu Desktop (GNOME2, then Unity) so as to get the desktop I really wanted, but then decided that wasn't necessary & it was often easier to have both installed; which allowed me to use the default GNOME2 which I loved, or Unity that didn't as much for me for a change)
If it was me, I'd keep your existing Ubuntu install, and just add ubuntu-mate-desktop
. In the past I was more selective and introduced smaller packages, but I found that more work (and results could vary on release) so now just use the full meta package.
Do note: All installs I have have multiple desktops installed; it's my preference, partially as I find different DEs more efficient for some tasks & I can select which I'll use at login for a session, but mostly as switching DEs allows me to work on my machine and yet have the machine feel slightly differently depending on whatever mood I feel like when I login & start my session. Most of my DEs are setup so they're visually similar (MATE, Xfce, LXQt, very loosely GNOME) though my media keys do act differently depending on which DE is used; and I've not tried to synchronize that.
My primary PC died recently, it was dual boot with kinetic (what was then the current development release, only recently released) & a LTS (focal or 20.04), with Ubuntu, Xubuntu, Lubuntu & Ubuntu-MATE desktops installed on each. I'm using another PC currently (alas not even Ubuntu, but Debian bookworm) and it has ~20 session choices available on login; ie. more bloated than my Ubuntu system(s). I believe all my systems have multiple DEs installed.
With Ubuntu, I find having two [DEs] won't have problems, with issues only to be expected when you get to four (generally). I've written about it here if interested (where I talk about the my recent primary PC that has a dead PSU which I hope soon to replace).
Also note there are other costs with multiple DEs; you'll have more options in the (more crowded) menus, and selecting the wrong user-app can cause execution penalties if it uses different libs/toolkits to your currently running Desktop (ie. user-app & DE may not share resources), but my own knowledge means I realize this & consider this before starting the app. I actually still use devices with only 1GB of RAM, thus consider this automatically, but it's not newbie friendly! With MATE & GNOME there is far less conflict than if a Qt/GTK desktop/app choice was made.